Impacts of Internally and Externally Mixed Anthropogenic Sulfate and Carbonaceous Aerosols on East Asian Climate

A coupled regional climate and aerosol-chemistry model, RIEMS 2.0 (Regional Integrated Environmental Model System for Asia), in which anthropogenic sulfate, black carbon, and organic carbon were assumed to be externally mixed (EM), internally mixed (IM) or partially internally mixed (IEM), was used to simulate the impacts of these anthropogenic aerosols on East Asian climate for the entire year of 2006. The distributions of aerosol mass concentration, radiative forcing and hence the surface air temperature and precipitation variations under three mixing assumptions of aerosols were analyzed. The results indicated that the mass concentration of sulfate was sensitive to mixing assumptions, but carbonaceous aerosols were much less sensitive to the mixing types. Modeled results were compared with observations in a variety of sites in East Asia. It was found that the simulated concentrations of sulfate and carbonaceous aerosols were in accord with the observations in terms of magnitude. The simulated aerosol concentrations in IM case were closest to observation results. The regional average column burdens of sulfate, black carbon, and organic carbon, if internally mixed, were 11.49, 0.47, and 2.17 mg m-2, respectively. The radiative forcing of anthropogenic aerosols at the top of the atmosphere increased from -1.27 (EM) to -1.97 W m-2 (IM) while the normalized radiative forcing (NRF) decreased from -0.145 (EM) to -0.139 W mg-1 (IM). The radiative forcing and NRF were -1.82 W m-2 and -0.141 W mg-1 for IEM, respectively. The surface air temperature changes over the domain due to the anthropogenic sulfate and carbonaceous aerosols were -0.067, -0.078, and -0.072 K, with maxima of -0.47, -0.50, and -0.49 K, for EM, IM, and IEM, respectively. Meanwhile, the annual precipitation variations were -8.0 (EM), -20.6 (IM), and -21.9 mm (IEM), with maxima of 148, 122, and 102 mm, respectively, indicating that the climate e?ects were stronger if the sulfate and carbonaceous aerosols were internally mixed.